New energetic nanomaterials synthesis

Synthesis of nanoparticles for energetic applications

Principal investigators: Angela Gondolini, Alessandra Sanson

Involved personnel: Elisa Mercadelli

Besides the process technologies used, the successful production of highly efficient ceramics is strictly related to the chemical-physical characteristics of the starting powders. For this objective, CNR-ISSMC has implemented a conventional synthesis method applying innovative heating systems for the production of ceria-based powders or perovskite-related systems with high chemical-physical reactivity and high purity and morphological control. These systems have been exploited for catalytic applications such as toluene synthesis and as high-efficient electrolytic powders for SOFC/SOEC applications as well as for solar conversion processes.

Equipment and processes

Micro-wave furnace

Conductivity of the CNR-ISTEC ceria doped gadolinium-GDC powder (on the left) and toluene conversion of the CNR-ISTEC cerium oxide powder (on the right). — The conductivity of the CNR-ISSMC ceria doped gadolinium-GDC powder (on the left) and toluene conversion of the CNR-ISSMC cerium oxide powder (on the right)

Main partners

Publications

Gondolini, E. Mercadelli, A. Sanson, S. Albonetti, L. Doubova, S. Boldrini, “Effect of the microwave heating on the properties of gadolinium-doped cerium oxide prepared by polyol method” Journal of the European Ceramic Society 33 (2013) 67-77.
Gondolini, E. Mercadelli, A. Sanson, S. Albonetti, L. Doubova, S. Boldrini “Microwave-assisted synthesis of gadolinia-doped ceria powders for solid oxide fuel cells”, Ceramics International 37 (2011) 1423-1426.
E. Mercadelli, G. Ghetti, A. Sanson, R. Bonelli, S. Albonetti “Synthesis of CeO2 nano-aggregates of complex morphology” Ceramics International 39 (2013) 629–634